H2 formation via the UV photo-processing of a-C:H nano-particles

Context. The photolysis of hydrogenated amorphous carbon, a-C(:H), dust by UV photon-irradiation in the laboratory leads to the release of H2 as well as other molecules and radicals. This same process is also likely to be important in the interstellar medium. Aims. To investigate molecule formation arising from the photo-dissociatively-driven, regenerative processing of a-C(:H) dust. Methods. We explore the mechanism of a-C(:H) grain photolysis leading to the formation of H2 and other molecules/radicals. Results. The rate constant for the photon-driven formation of H2 from a-C(:H) grains is estimated to be 2x10^-17 cm^3 s^-1. In intense radiation fields photon-driven grain decomposition will lead to fragmentation into daughter species rather than H2 formation. Conclusions. The cyclic re-structuring of arophatic a-C(:H) nano-particles appears to be a viable route to formation of H2 for low to moderate radiation field intensities (1 < G_0 < 10^2), even when the dust is warm (T ~ 50 - 100 K).Comment: 7 pages, 2 figures, accepted for publication in A&

Diamonds in HD 97048

We present adaptive optics high angular resolution (\sim0\farcs1) spectroscopic observations in the 3 $\mu$m region of the Herbig Ae/Be star HD 97048. For the first time, we spatially resolve the emission in the diamond features at 3.43 and 3.53 $\mu$m and in the adjacent continuum. Using both the intensity profiles along the slit and reconstructed two-dimensional images of the object, we derive full-width at half-maximum sizes consistent with the predictions for a circumstellar disk seen pole-on. The diamond emission originates in the inner region ($R \lesssim 15$ AU) of the disk.Comment: ApJLetter, in pres

Molecular hydrogen in the disk of the Herbig Ae star HD97048

We present high-resolution spectroscopic mid-infrared observations of the circumstellar disk around the Herbig Ae star HD97048 obtained with the VLT Imager and Spectrometer for the mid-InfraRed (VISIR). We conducted observations of mid-infrared pure rotational lines of molecular hydrogen (H2) as a tracer of warm gas in the disk surface layers. In a previous paper, we reported the detection of the S(1) pure rotational line of H2 at 17.035 microns and argued it is arising from the inner regions of the disk around the star. We used VISIR on the VLT for a more comprehensive study based on complementary observations of the other mid-infrared molecular transitions, namely S(2) and S(4) at 12.278 microns and 8.025 microns respectively, to investigate the physical properties of the molecular gas in the circumstellar disk around HD97048. We do not detect neither the S(2) line nor the S(4) H2 line from the disk of HD97048, but we derive upper limits on the integrated line fluxes which allows us to estimate an upper limit on the gas excitation temperature, T_ex < 570 K. This limit on the temperature is consistent with the assumptions previously used in the analysis of the S(1) line, and allows us to set stronger contraints on the mass of warm gas in the inner regions of the disk. Indeed, we estimate the mass of warm gas to be lower than 0.1 M_Jup. We also discuss the probable physical mechanisms which could be responsible of the excitation of H2 in the disk of HD97048.Comment: accepted for publication in Ap

Where is the warm H2 ? A search for H2 emission from disks around Herbig Ae/Be stars

Mid-IR emission lines of H2 are useful probes to determine the mass of warm gas present in the surface layers of disks. Numerous observations of Herbig Ae/Be stars (HAeBes) have been performed, but only 2 detections of mid-IR H2 toward HD97048 and AB Aur have been reported. We aim at tracing the warm gas in the disks of 5 HAeBes with gas-rich environments and physical characteristics close to those of AB Aur and HD97048, to discuss whether the detections toward these 2 objects are suggestive of peculiar conditions for the gas. We search for the H2 S(1) emission line at 17.035 \mu\m with VISIR, and complemented by CH molecule observations with UVES. We gather the H2 measurements from the literature to put the new results in context and search for a correlation with some disk properties. None of the 5 VISIR targets shows evidence for H2 emission. From the 3sigma upper limits on the integrated line fluxes we constrain the amount of optically thin warm gas to be less than 1.4 M_Jup in the disk surface layers. There are now 20 HAeBes observed with VISIR and TEXES instruments to search for warm H2, but only two detections (HD97048 and AB Aur) were made so far. We find that the two stars with detected warm H2 show at the same time high 30/13 \mu\m flux ratios and large PAH line fluxes at 8.6 and 11.3 \mu\m compared to the bulk of observed HAeBes and have emission CO lines detected at 4.7 \mu\m. We detect the CH 4300.3A absorption line toward both HD97048 and AB Aur with UVES. The CH to H2 abundance ratios that this would imply if it were to arise from the same component as well as the radial velocity of the CH lines both suggest that CH arises from a surrounding envelope, while the detected H2 would reside in the disk. The two detections of the S(1) line in the disks of HD97048 and AB Aur suggest either peculiar physical conditions or a particular stage of evolution.Comment: accepted for publication in A&A : 10 pages, 6 figure

Aromatic emission from the ionised mane of the Horsehead nebula

We study the evolution of the Aromatic Infrared Bands (AIBs) emitters across the illuminated edge of the Horsehead nebula and especially their survival and properties in the HII region. We present spectral mapping observations taken with the Infrared Spectrograph (IRS) at wavelengths 5.2-38 microns. A strong AIB at 11.3 microns is detected in the HII region, relative to the other AIBs at 6.2, 7.7 and 8.6 microns. The intensity of this band appears to be correlated with the intensity of the [NeII] at 12.8 microns and of Halpha, which shows that the emitters of the 11.3 microns band are located in the ionised gas. The survival of PAHs in the HII region could be due to the moderate intensity of the radiation field (G0 about 100) and the lack of photons with energy above about 25eV. The enhancement of the intensity of the 11.3 microns band in the HII region, relative to the other AIBs can be explained by the presence of neutral PAHs. Our observations highlight a transition region between ionised and neutral PAHs observed with ideal conditions in our Galaxy. A scenario where PAHs can survive in HII regions and be significantly neutral could explain the detection of a prominent 11.3 microns band in other Spitzer observations.Comment: 9 pages, 9 figures, accepted for publication in A&

HerschelHerschel SPIRE-FTS observations of RCW 120

The expansion of Galactic HII regions can trigger the formation of a new generation of stars. However, little is know about the physical conditions that prevail in these regions. We study the physical conditions that prevail in specific zones towards expanding HII regions that trace representative media such as the photodissociation region, the ionized region, and condensations with and without ongoing star formation. We use the SPIRE Fourier Transform Spectrometer (FTS) on board $Herschel$ to observe the HII region RCW 120. Continuum and lines are observed in the $190-670\,\mu$m range. Line intensities and line ratios are obtained and used as physical diagnostics of the gas. We used the Meudon PDR code and the RADEX code to derive the gas density and the radiation field at nine distinct positions including the PDR surface and regions with and without star-formation activity. For the different regions we detect the atomic lines [NII] at $205\,\mu$m and [CI] at $370$ and $609\,\mu$m, the $^{12}{\rm CO}$ ladder between the $J=4$ and $J=13$ levels and the $^{13}{\rm CO}$ ladder between the $J=5$ and $J=14$ levels, as well as CH$^{+}$ in absorption. We find gas temperatures in the range $45-250\,$K for densities of $10^4-10^6\,{\rm cm}^{-3}$, and a high column density on the order of $N_{{\rm H}}\sim10^{22}\,{\rm cm}^{-2}$ that is in agreement with dust analysis. The ubiquitousness of the atomic and CH$^{+}$ emission suggests the presence of a low-density PDR throughout RCW 120. High-excitation lines of CO indicate the presence of irradiated dense structures or small dense clumps containing young stellar objects, while we also find a less dense medium ($N_{{\rm H}}\sim10^{20}\,{\rm cm}^{-2}$) with high temperatures ($80-200\,$K).Comment: 11 pages, 11 figures, accepted by A&

Density structure of the Horsehead nebula photo-dissociation region

We present high angular resolution images of the H$_2$ 1-0 S(1) line emission obtained with the Son of ISAAC (SOFI) at the New Technology Telescope (NTT) of the Horsehead nebula. These observations are analysed in combination with H$\alpha$ line emission, aromatic dust, CO and dust continuum emissions. The Horsehead nebula illuminated by the O9.5V star $\sigma$ Ori ($\chi \sim$ 60) presents a typical photodissociation region (PDR) viewed nearly edge-on and offers an ideal opportunity to study the gas density structure of a PDR. The H$_2$ fluorescent emission observations reveal extremely sharp and bright filaments associated with the illuminated edge of the nebula which spatially coincides with the aromatic dust emission. Analysis of the H$_2$ fluorescent emission, sensitive to both the far-UV radiation field and the gas density, in conjunction with the aromatic dust and H$\alpha$ line emission, brings new constraints on the illumination conditions and the gas density in the outer PDR region. Furthermore, combination of this data with millimeter observations of CO and dust continuum emission allows us to trace the penetration of the far-UV radiation field into the cloud and probe the gas density structure throughout the PDR. From comparison with PDR model calculations, we find that i) the gas density follows a steep gradient at the cloud edge, with a scale length of 0.02 pc (or 10'') and $n_H\sim 10^4$ and $10^5$ cm$^{-3}$ in the H$_2$ emitting and inner cold molecular layers respectively, and ii) this density gradient model is essentially a constant pressure model, with $P\sim$4 $10^6$ K cm$^{-3}$. The constraints derived here on the gas density profile are important for the study of physical and chemical processes in PDRs and provide new insight into the evolution of interstellar clouds.Comment: To be published in A&

Dust processing in photodissociation regions - Mid-IR emission modelling

Mid-infrared spectroscopy of dense illuminated ridges (or photodissociation regions, PDRs) suggests dust evolution. Such evolution must be reflected in the gas physical properties through processes like photo-electric heating or H_2 formation. With Spitzer Infrared Spectrograph (IRS) and ISOCAM data, we study the mid-IR emission of closeby, well known PDRs. Focusing on the band and continuum dust emissions, we follow their relative contributions and analyze their variations in terms of abundance of dust populations. In order to disentangle dust evolution and excitation effects, we use a dust emission model that we couple to radiative transfer. Our dust model reproduces extinction and emission of the standard interstellar medium that we represent with diffuse high galactic latitude clouds called Cirrus. We take the properties of dust in Cirrus as a reference to which we compare the dust emission from more excited regions, namely the Horsehead and the reflection nebula NGC 2023 North. We show that in both regions, radiative transfer effects cannot account for the observed spectral variations. We interpret these variations in term of changes of the relative abundance between polycyclic aromatic hydrocarbons (PAHs, mid-IR band carriers) and very small grains (VSGs, mid-IR continuum carriers). We conclude that the PAH/VSG abundance ratio is 2.4 times smaller at the peak emission of the Horsehead nebula than in the Cirrus case. For NGC2023 North where spectral evolution is observed across the northern PDR, we conclude that this ratio is ~5 times lower in the dense, cold zones of the PDR than in its diffuse illuminated part where dust properties seem to be the same as in Cirrus. We conclude that dust in PDRs seems to evolve from "dense" to "diffuse" properties at the small spatial scale of the dense illuminated ridge.Comment: 11 pages, 11 figures, accepted for publication in A&

Nano-grain depletion in photon-dominated regions

Context. Carbonaceous nano-grains play a fundamental role in the physico-chemistry of the interstellar medium (ISM) and especially of photon-dominated regions (PDRs). Their properties vary with the local physical conditions and affect the local chemistry and dynamics. Aims. We aim to highlight the evolution of carbonaceous nano-grains in three different PDRs and propose a scenario of dust evolution as a response to the physical conditions. Methods. We used Spitzer/IRAC (3.6, 4.5, 5.8, and 8 $\mu$m) and Spitzer/MIPS (24 $\mu$m) together with Herschel/PACS (70 $\mu$m) to map dust emission in IC63 and the Orion Bar. To assess the dust properties, we modelled the dust emission in these regions using the radiative transfer code SOC together with the THEMIS dust model. Results. Regardless of the PDR, we find that nano-grains are depleted and that their minimum size is larger than in the diffuse ISM (DISM), which suggests that the mechanisms that lead nano-grains to be photo-destroyed are very efficient below a given critical size limit. The evolution of the nano-grain dust-to-gas mass ratio with both G0 and the effective temperature of the illuminating star indicates a competition between the nano-grain formation through the fragmentation of larger grains and nano-grain photo-destruction. We modelled dust collisions driven by radiative pressure with a classical 1D approach to show that this is a viable scenario for explaining nano-grain formation through fragmentation and, thus, the variations observed in nano-grain dust-to-gas mass ratios from one PDR to another. Conclusions. We find a broad variation in the nano-grain dust properties from one PDR to another, along with a general trend of nano-grain depletion in these regions. We propose a viable scenario of nano-grain formation through fragmentation of large grains due to radiative pressure-induced collisions